Optimization of a methane autothermal reforming bas ed hydrogen production system with low co 2 emissions wei wu,a and chutima tungpanututh b adepartment of chemical engineering, national cheng kung university, tainan 70101, taiwan, r. It includes simultaneous consideration of kinetics and heat transfer, both critical to the performance of real chemical reactors. Autothermal reforming an overview sciencedirect topics. With this in mind, this course nuclear reactor theory is designed for students who are studying nuclear engineering for the first time. Steam reforming is the established process for h 2 production and for syngas production for the manufacture of methanol. D stationary reactor model describes the catalytic conversion of a gaseous hydrocarbon fuel with air and steam to synthesis gas by autothermal reforming and catalytic partial oxidation. Reactor with lowest rate of consumption determines which reactor has the lowest consumption rate of reactant at the reactor outlet.
To these ends, a design comprising 5 sections both for the reforming and the combustion sides loaded with monoliths of 2 rows in height and 30 channels in width is selected i. Advanced modelling and optimisation of natural gas. Using the 1d reactor model previously described and validated at labscale, the design and heat management of an industrialscale chemical looping reforming reactor system have been carried out for integration in both h 2 and ch 3 oh plants. Hydrogen production by steam reforming in palladium membrane reactors. Goodreads helps you keep track of books you want to read. Pdf optimal design, modeling and simulation of an ethanol. Natural circulation in reactor engineering natural circulation in a closed loop.
Heat and mass transfer correlations for steam methane reforming. Two of the referred reactors, usually atr, smr or her, are arranged in series or parallel. Nonisothermal reactor design if you cant stand the heat. Equilibirium gibbs reactor with 20f approach for design. The simulation model of srm is onedimensional model, which is not considered any dimensions, reactor design, velocity, reaction rate, and catalyst effect. Ive been seeing a lot of reactor designs on here, but unless ive missed something none of them appear to scale proportionally.
If you continue browsing the site, you agree to the use of cookies on this website. Hydrogen from natural gas via steam methane reforming smr. Basic objectives in design of a reactor in chemical engineering physical operations such as fluid flow, heat transfer, mass transfer and separation processes play a very large part. Feb 05, 2015 second order reaction times batch reactor procedure get the design equation for the batch in terms of concentration or conversion for 1 rxn if no rate of reaction vs. Second order reaction times batch reactor procedure get the design equation for the batch in terms of concentration or conversion for 1 rxn if no rate of reaction vs. Preliminary equipment design for onboard hydrogen production. The reactor core can be either a prismaticblock or a pebble bed reactor design. Under this approach the license includes permission to both build a reactor and operate it later, as long as a detailed list of completion requirements are met. Adiabatic determines if it is better to run a reaction isothermally or adiabatically to achieve a high selectivity to the desired product. Consider the reversible gas phase elementary reaction. Reactor by adam petersen this final part of the series will step outside the domain of standard c and investigate a pattern for eventdriven applications. The nreactor was a watergraphitemoderated nuclear reactor constructed during the cold war and operated by the u. N reactor had a stateoftheart cooling system, which required significantly less columbia river water to be used to cool it during operations.
Twostep or combined reforming reactors are also important reactor configurations. Tubular reactor systems with special molten salt technology tubular reactors with air, oil, boiling and pressurewater cooling special designed reactors, pilot reactors and pilot plant studies. In pwrs, plant design provides an elevation difference, h, of approximately 12 meters between the centerline. However, higher pressures also require a higher reactor temperature to achieve high methane conversion. Natural circulation in reactor engineering nuclear power. Proven autothermal reforming technology for modern large. The basic design equations, rate laws, and stoichiomctrjc relationships derived and. I decided to go with a columnar design where the heat exchangers, steam turbines, assemblers for unbarreling water, and pumps were all stacked vertically in units that scaled exactly with the power produced by the reactors occupying the same width as the column.
The dry methane reforming reaction is favored by low pressure, but high pressure synthesis gas is required in the downstream process. All of the heat exchanger blocks are wider than the reactor blocks. Physics books nuclear physics books nuclear reactor theory pdf 115p advertisement. A combined license includes the same 40year operating period as the licenses for todays reactors. The new design houses the reactors main components, including the graphite, in a sealed unit that can be swapped out every seven years, theoretically making operating the. Design aspects of membrane reactors for dry reforming of. Nuclear power is often perceived as a technology that defies the natural order but simply head to africa and youll find the worlds first and only natural nuclear. The experimental effort was then focused on a series of measurements to evaluate rich, highpressure burner behavior at pressures as high as 500 psi.
Actually, one of the things that makes reactors safe for naval ships vs. Nuclear reactor design an advanced course in nuclear. Chaplin encyclopedia of life support systems eolss 1. Reactor physicsthe diffusion of neutronspdf 29p download book. It is based on advances made in nuclear power utilization and computational methods over the past 40 years, covering core design of boiling water reactors and pressurized water reactors, as well as fast reactors and hightemperature gascooled reactors. The high temperatures enable applications such as process heat or. Such a design offers a number of advantages for hydrogen. Where k c is the concentration equilibrium constant. In any manufacturing process where there is a chemical change. An experimental reactor called sl1 stationary lowpower plant number 1 was destroyed when a control rod was pulled too far out of the reactor, leading to core meltdown and a steam explosion. Speight phd, dsc, in gasification of unconventional feedstocks, 2014. A reactor is a system in which a particular substance, when put under a specific set of circumstances, reacts in a way which is used to generate energy. Batch reactor given its volume v, and the initial internal concentration c0, the total mass will be m vc0.
Various organizations have built more than 50 reactors at what is commonly called the site, including the ones that gave. Iss consists of the removal of the fuel storage basin, ancillary support facilities, and most portions of the shield wall that surround the 105n reactor. This note will cover a range of topics pertinent to nuclear engineering, including particle physics, neutron theory, nuclear reactor design, medical applications, societal impacts of nuclear power. Higher reactor pressures reduce compression costs of the synthesis gas. Nuclear reactor design encyclopedia of life support systems. Microchannel reactors may offer distinct advantages in process development and. Proven autothermal reforming technology for modern largescale methanol plants per juul dahl thomas s. Autothermal reforming atr is an important industrial process used to produce syngas with a low h2co ratio from 1. If there was ever a loss of cooling water, n was built with an automatic safety system in place that would shut down the reactor on its own without any operator action required.
Autothermal reforming of natural gas to synthesis gas. Optimization of a methane autothermal reformingbased. Steadystate nonisothermal reactor design if you cant stand the heat. The european sustainable nuclear industrial initiative is funding three generation iv reactor systems, one of which is a sodiumcooled fast reactor, called astrid, advanced sodium technical reactor for industrial demonstration, areva, cea and edf are leading the design with british collaboration. Bibliography the books here quoted have to be used for reference only, as they are too advanced for the purpose of this class. Everyday low prices and free delivery on eligible orders. The 48% of current hydrogen production is via steam reforming of natural gas. Design of reactor for modeling of heat transfer and kinetics.
On january 3, 1961, the only fatal nuclear reactor incident in the u. Consider an exothermic reaction where the coolant stream enters at the end of the reactor at a temperature t a0, say 300 k. The model defines two subsequent sections in the reactor. Assume a coolant temperature at the entrance x 0, v 0 to the reactor t a2 340 k. These new reactors are authorized through the nrcs combined license process. The design put forward by westinghouse, the american firm now owned by toshiba of japan, is also criticised, with the hse saying the safety case on internal hazards has significant shortfalls. Design and control of the dry methane reforming process.
In this case, the operating conditions of the onboard reformer are t 650 c. Modeling and simulation of methanation catalytic reactor in ammonia unit. Process analysis of solar steam reforming of methane for producing. Modern reactor designs use natural circulation a very important safety feature. Compact steammethane reforming for the production of hydrogen. Nuclear regulatory commission nrc approves a nuclear power plant design, independent of an application to construct or operate a plant. Natural gas reforming is carried out in multitubular fixed bed reactors using an external furnace to provide the heat of reaction ftr or in an autothermal reforming atr system using an oxidant i. In its design, the n reactor shared many features with the eight older reactors on the. In reactor engineering, natural circulation is very desired phenomenon, since it is capable to provide reactor core cooling after the loss of rcps e. Reactor by adam petersen this final part of the series will step outside the domain of standard c and investigate a. The nuclear fuel, often uranium oxide, is packaged as long, thin rods. N reactor the 105n reactor and the 109n heat exchanger building were placed in interim safe storage iss in 2012. Schematic representation of steam reformer sr, membrane reactor mr.
Transport phenomena for chemical reactor design approaches the design of chemical reactors from microscopic heat and mass transfer principles. We know from le chaltliers law that if the reaction is exothermic, k c will decrease as the temperature is increased and the reaction will be shifted back to the left. Buy nuclear reactor design an advanced course in nuclear engineering 2014 by oka, yoshiaki, kiguchi, takashi isbn. Conversion is given you need a rate law substitute the rate law in the design equation develop mathematically analytical solution if possible. Reactor design is primarily concerned with the type and size of the reactor and its method of operation for the required process.
Hanfords n reactor, designed to produce both plutonium for weapons and electricity for the public, was the ninth and final reactor to be constructed at the hanford nuclear reservation, located along the columbia river in benton county. Chemical reaction and reactor design begins with a discussion of chemical reactions, emphasizing chemical equilibrium and rate of reaction and proceeds to the theory and practice of heat and mass transfer, and important considerations in the design of chemical reactors. Before getting into new designs, take a look at todays reactor designs, which date from the 1960s. Optimum temperature progression in tubular reactor. A design certification is valid for 15 years from the date of issuance, but can be renewed for an additional 10 to 15 years. The largest part of the price tag would be research, development, and design work to develop and test a new reactor design. The combined mole balance, rate law, and stoichiometry yield. In the unit time, the concentration will be able to change only in virtue of a chemical reaction.
In addition, the 109n heat exchanger building was removed up to the. The basic design equations, rate laws, and stoichiomctrjc relationships derived and used in chapter 4 for isothermal reactor design are. Nov 26, 2009 the design put forward by westinghouse, the american firm now owned by toshiba of japan, is also criticised, with the hse saying the safety case on internal hazards has significant shortfalls. A three dimensional monolithic reactor was modeled in the second part of the report, combining. Purchase thermal design of nuclear reactors 1st edition.
Jan 22, 2015 the new design houses the reactors main components, including the graphite, in a sealed unit that can be swapped out every seven years, theoretically making operating the plant easier. Optimal design, modeling and simulation of an ethanol steam reforming reactor article pdf available in international journal of chemical reactor engineering 71. Steady state nonisothermal reactor design energy balances, rationale and overview calculate the volume necessary to achieve a conversion, x, in a pfr for a firstorder, exothermic reaction carried out adiabatically. Start by marking introduction to nuclear reactor theory as want to read. The reactor design of the atr, as well as oxygenblown secondary reformers, consists of a burner, a. Im happy to say ive come up with a design that doesnt have this problem.
Resurrecting a meltdownproof reactor design mit technology. Mar 22, 2017 these new reactors are authorized through the nrcs combined license process. Infinitely scaling nuclear reactor design tested to 20gw. Because most reactions we not carried out isothermally, we now focus our attention on heat effecrs in chemical reactors. Part 1 elements of nuclear reactor theory is composed of only elements but the main resource for the lecture of nuclear reactor theory, and. Water contents in the reforming feed is selected to meet a steamtocarbon ratio of 3, the double. A twostep reforming unit consists of a steam reformer, which includes a. This book focuses on core design and methods for design and analysis. Design of reactor for modeling of heat transfer and. While the laboratory does other research, historically it has been involved with nuclear research. This paper presents an evaluation of various plant designs incorporating high temperature membranes for the dryreforming reaction of methane for hydrogen.
Special relativity, schroedingers wave equation, nuclear models, nuclear decay kinetics. The size of the reactors is based on commercial largescale plants. Selectivity determines how selectivity changes at the outlet of a cstr if another cstr is added in series determining reaction rate order for a batch reactor evaluates the. Idaho national laboratory inl is one of the national laboratories of the united states department of energy and is managed by the battelle energy alliance. Fission chain reaction when the nucleus of a fissile material such as uranium235 is induced to fission by the absorption of a neutron, two to three neutrons, on average, are released as the two fission. Cstr calculates if the conversion in a 100 l adiabatic cstr is greater than, less than, or equal to the conversion in a 100 l adiabatic pfr cstrs in series. The rate law for this gas phase reaction will follow an elementary rate law. Tubular reactor systems with special molten salt technology tubular reactors with air, oil, boiling and pressurewater cooling special designed reactors, pilot reactors and. The design of any process where chemical reaction is required is given due consideration. Cumulative concentration curves for different numbers of cstr in series. Chemicalpolymer reactor design muhammad zafar iqbal slideshare uses cookies to improve functionality and performance, and to provide you with relevant advertising. Many passive safety systems in modern reactor designs operate without using any pumps, which creates increased design safety, integrity, and reliability, while simultaneously reducing overall reactor cost. The final section of the book provides detailed case studies from the chemical industry covering the six chemical processes.